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SAE 2017-01-0910

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Abstract

We studied the mechanism of NO reduction as well as its selectivity and reactivity in the presence of excess O 2 . Results show that fuel injection and/or pretreatment are important for ceria catalyst reduction and carbon deposition on the catalyst surface. Oxygen defects of reduced ceria are the key sites for the reduction of NO into N 2 . The deposited carbon acts as a buffer reductant, i.e., the oxidation of carbon by lattice oxygen recreates oxygen defects to extend the NO reduction time interval. A small amount of NO showed a full conversion into only N 2 both on the reduced Zr-La doped ceria and reduced Pt-Zr-La doped ceria. Only when the catalyst is oxidised NO is converted into NO 2 .

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  • Standard from SAE International
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  • Document type: IS
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  • Publisher: SAE International
  • Distributor: SAE International